Effect of sweeping voltage and compliance current on bipolar resistive switching and white-light controlled Schottky behavior in epitaxial BaTiO3 (111) thin films

Bipolar resistive switching (RS) phenomenon without required electroforming has been observed in epitaxial (111)-oriented BaTiO₃ (BTO) thin films deposited by PLD technique on conducting Nb-doped substrate of SrTiO₃ (NSTO). Negative differential resistance (NDR) is observed at about −5 V when the maximum of positive voltage exceeds 7 V and the compliance current is more than 1.5 mA. And bipolar resistive switching has also been observed. In addition, the resistance of LRS decreases with increasing compliance current or the maximum of positive voltage while that of HRS barely changes, and the resistance of HRS increases with increasing the absolute of maximum of negative voltage while that of LRS scarcely changes. A typical rectifying behavior is observed when the maximum of positive voltage is less than 4 V (such as 2 V). In this case, the reverse biased current is strongly enhanced under illumination of white-light, and vice versa. The resistance of LRS and HRS can be controlled by the applied voltage or the compliance current. The rectifying behavior can be controlled by the white-light. The transition from rectifying behavior to bipolar resistive switching can be controlled by the applied voltage. The above results were discussed by considering the oxygen vacancies that can trap or release electrons as a trapping layer at the Pt/BTO interface.     

Effect of scandia content on the thermal shock behavior of SYSZ thermal sprayed barrier coatings

Nanostructured 4SYSZ (scandia (3.5 mol%) yttria (0.5 mol%) stabilized zirconia) and 5.5 SYSZ (5 mol% scandia and 0.5 mol% yttria) thermal barrier coatings (TBCs) were deposited on nickel-based superalloy using NiCrAlY as the bond coat by plasma spraying process. The thermal shock response of both as-sprayed TBCs was investigated at 1000 °C. Experimental results indicated that the nanostructured 5.5SYSZ TBCs have better thermal shock performance in contrast to 4SYSZ TBCs due to their higher tetragonal phase content and higher fracture toughness of this coating     

An adaptive Tikhonov regularization parameter choice method for electrical resistance tomography

Electrical resistance tomography (ERT) reconstructs the conductivity distribution from the boundary changes of electrical measurements. The inverse problem of ERT is seriously ill-posed where regularization methods are needed to treat this ill-posedness. A proper choice of regularization parameter which controls the degree of smoothing is very important for these regularization methods. Although have been a variety of methods, such as L-curve method, to choose a reasonable parameter for the problem, these methods usually result in a scalar parameter which cannot distinctly express the spatial characteristic of the conductivity distribution. So a spatially adaptive regularization parameter choice method is proposed for regularizing the inverse problem of ERT based on Tikhonov regularization. Since large regularization parameters can stabilize and smoothen the solution, while small regularization parameters can approximate and sharpen the solution, the proposed method adaptively updates the regularization parameters during the iteration process and provides spatially varying parameter for each pixel of the reconstructed image. When the iteration is stopped, large regularization parameters for the smooth background region and small regularization parameters for the object region can be obtained. The method is discussed using simulated data for some typical conductivity distributions, and further applied to the analysis of real measurement data acquiring from the practical system. The results demonstrate that flexible regularization parameter vectors can be achieved for different distributions and the strength of regularization is adaptively provided for different regions in a specific distribution. The adaptive method achieves an efficient and reliable regularization solution and has outstanding performance in noise immunity especially in smooth background regions.     

Effects of Rare Earth,Titanium, and Magnesium Additions on Microstructures and Properties of High-boron Medium-carbon Alloy

In order to improve the toughness and wear resistance of high-boron medium-carbon alloy(HBMCA),a novel wear-resistant HBMCA comprising granular borocarbide was obtained by titanium,magnesium,and rare earth modifications.These modifications gave rise to greatly refined as-cast eutectic borocarbide structures and a less interconnected continuous borocarbide network.Heat treatment mostly produced broken and spheriodized borocarbides that tended to exist as isolated particles in modified HBMCA.The heat treated modified HBMCA exhibited enhanced hardness than pristine and impact toughness was improved significantly to 12.5J/cm~2.In addition,it displayed 2.39 and 1.7times greater wear resistance than high-speed steel(HSS)and high nickel-chromium alloy steel(Cr25)at high temperature(500℃),respectively.Here,the modification mechanisms involving Re_2O_3,TiN,and MgO/MgS heterogeneous nuclei were discussed.     

Quantitative evaluation of malignant gliomas damage induced by photoactivation of IR700 dye

The processes involved in malignant gliomas damage were quantitatively evaluated by microscopy. The near-infrared fluorescent dye IR700 that is conjugated to an anti-CD133 antibody (IR700-CD133) specifically targets malignant gliomas (U87MG) and stem cells (BT142) and is endocytosed into the cells. The gliomas are then photodamaged by the release of reactive oxygen species (ROS) and the heat induced by illumination of IR700 by a red laser, and the motility of the vesicles within these cells is altered as a result of cellular damage. To investigate these changes in motility, we developed a new method that measures fluctuations in the intensity of phase-contrast images obtained from small areas within cells. The intensity fluctuation in U87MG cells gradually decreased as cell damage progressed, whereas the fluctuation in BT142 cells increased. The endocytosed IR700 dye was co-localized in acidic organelles such as endosomes and lysosomes. The pH in U87MG cells, as monitored by a pH indicator, was decreased and then gradually increased by the illumination of IR700, while the pH in BT142 cells increased monotonically. In these experiments, the processes of cell damage were quantitatively evaluated according to the motility of vesicles and changes in pH.     

深海油气输送用X70厚壁直缝埋弧焊钢管的耐蚀性

开发试制了深海油气输送用X70厚壁直缝埋弧焊(LSAW)钢管(1 016mm,壁厚36.5mm),对管线钢的化学成分、组织和力学性能进行了分析,并通过氢致开裂(HIC)、硫化物应力腐蚀(SSC)、腐蚀浸泡等试验研究了钢管管体及焊接接头的耐腐蚀性能。结果表明:该试验钢管的管体及焊接接头具有良好的抗氢致开裂和抗硫化物应力腐蚀开裂性能,腐蚀速率小于0.09mm/a,可用于具有腐蚀性的海洋环境中。     

Parameterisation of a biodiesel plant process flow sheet model

This paper presents results of parameterisation of typical input–output relations within process flow sheet of a biodiesel plant and assesses parameterisation accuracy. A variety of scenarios were considered: 1, 2, 6 and 11 input variables (such as feed flow rate or a heater's operating temperature) were changed simultaneously, 3 domain sizes of the input variables were considered and 2 different surrogates (polynomial and high dimensional model representation (HDMR) fitting) were used. All considered outputs were heat duties of equipment within the plant. All surrogate models achieved at least a reasonable fit regardless of the domain size and number of dimensions. Global sensitivity analysis with respect to 11 inputs indicated that only 4 or fewer inputs had significant influence on any one output. Interaction terms showed only minor effects in all of the cases.     

Materials resistance to corrosion by I2–HI–H2O mixtures for the realization of a sulfur-iodine plant

The substances involved in the sulfur-iodine (SI) thermochemical cycle to produce H₂ by water splitting are very corrosive and may attack reactors, pumps, catalysts supports, and whatever part of the plant. This paper investigates the corrosion exerted by HI solutions in liquid, boiling, and gaseous phase at different temperatures. It shows the broadest overview of the behavior of different materials, ranging from pure metals to metallic alloys, from carbon materials to organic polymers, from ceramic materials to composite ones. Commercial nickel alloys and the effect of a specific element in their composition have here considerable attention. Regarding the composites materials, the impact of the substrate as well as the coating nature and thickness is studied, also through SEM-EDS (Scan Electron Microscope Energy Dispersive Spectroscopy) investigations.Carbon materials performed well, while most of the analyzed materials showed intergranular corrosion, pitting phenomena, and sometimes, carbide precipitation in the higher energy zones.     

Fabrication of a double-layered Co-Mn-O spinel coating on stainless steel via the double glow plasma alloying process and preoxidation treatment as SOFC interconnect

To improve oxidation resistance, prevent Cr evaporation and maintain appropriate electrical conductivity of AISI 430 stainless steel (430 SS) as the solid oxide fuel cells' (SOFCs) interconnect, a double-layered Co-Mn-O spinel coating is fabricated successfully on 430 SS via a simple double glow plasma alloying process (DGPA) followed by heating in the air (preoxidation treatment). The double-layered Co-Mn-O spinel coating is composed of a thick MnCo₂O₄ spinel outlayer and a thin mutual-diffused (MnCoFe)₃O₄ oxide innerlayer. The isothermal and cyclic oxidation measurements are used to investigate the oxidation resistance, and the ASR test is performed to evaluate the conductivity for the coated and uncoated specimens. The coated specimen has a lower oxidation kinetics rate constant (9.0929 × 10⁻⁴ mg² cm⁻⁴ h⁻¹) than the uncoated one (1.900 × 10⁻³ mg² cm⁻⁴ h⁻¹) and the weight gain of the coated specimen (0.84 mg cm⁻²) is less than that of bare steel (1.29 mg cm⁻²) after 750 h oxidation. Meanwhile, the coated specimen holds a lower area specific resistance (0.029 Ω cm²) compared to the uncoated one (2.28 Ω cm²) after 408 h oxidation. Furthermore, the compact Co-Mn-O spinel coating can effectively impede Cr-volatilization. Additionally, the probable mechanism of the Co-Mn alloy conversion into spinel and the electronic conduction behavior in the spinel are discussed. The effects of mutual-diffused oxide innerlayer on oxidation behavior and conductivity are investigated.